VLO / Valero Energy Corporation - SEC-Einreichungen, Jahresbericht, Proxy Statement

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): May 7, 2026 VALERO ENERGY CORPORA

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): May 7, 2026 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commission F

CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002

Exhibit 31.02 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Homer S. Bhullar, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances

CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002

Exhibit 31.01 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, R. Lane Riggs, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances und

Valero Energy Reports First Quarter 2026 Results

Exhibit 99.01 Valero Energy Reports First Quarter 2026 Results •Reported net income attributable to Valero stockholders of $1.3 billion, or $4.22 per share •Increased quarterly cash dividend on common stock by 6 percent to $1.20 per share on January 22, 2026 •Issued $850 million aggregate principal amount of 5.150% Senior Notes due 2036 for debt repayment and general corporate purposes on March 10

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): April 30, 2026 VALERO ENERGY CORP

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): April 30, 2026 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commissio

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q (Mark One) ☑ QUARTERLY REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the quarterly period ended March 31, 2026 OR ☐ TRANSITION REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to Commission File Number 001-13175 VALERO ENE

CERTIFICATION PURSUANT TO 18 U.S.C. SECTION 1350, AS ADOPTED PURSUANT TO SECTION 906 OF THE SARBANES-OXLEY ACT OF 2002

Exhibit 32.01 CERTIFICATION PURSUANT TO 18 U.S.C. SECTION 1350, AS ADOPTED PURSUANT TO SECTION 906 OF THE SARBANES-OXLEY ACT OF 2002 In connection with the Quarterly Report of Valero Energy Corporation (the Company) on Form 10-Q for the quarter ended March 31, 2026, as filed with the Securities and Exchange Commission on the date hereof (the Report), the undersigned hereby certifies, pursuant to 1

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 (Amendment No. )

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 (Amendment No. ) Filed by the Registrant ☒ Filed by a party other than the Registrant ☐ Check the appropriate box: ☐ Preliminary Proxy Statement ☐ Confidential, for Use of the Commission Only (as permitted by Rule 14a-6(e)(2)) ☒ Defin

ARS

2026 Notice of Annual Meeting of Stockholders PROXY STATEMENT & ANNUAL REPORT ON FORM 10-K*DI>8:
D;

CCJ6A
)::I>C<
D;
/ID8@=DA9:GH 3A>

:GGN:E
F>>MBG@
H?
LMHKL
H?
5:E>KH
$G>K@R
"HKIHK :MBHG
BL
L=NE>=
MH
;>
A>E=
BG
:
OBKMN:E
?HKF:M
:L
?HEEHPL )!!0%*#
0!

0%)! )!!0%*#
/%0! .

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 (Amendment No. )

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 (Amendment No. ) Filed by the Registrant ☒ Filed by a party other than the Registrant ☐ Check the appropriate box: ☐ Preliminary Proxy Statement ☐ Confidential, for Use of the Commission Only (as permitted by Rule 14a-6(e)(2)) ☐ Defin

$850,000,000 Valero Energy Corporation 5.150% Senior Notes due 2036

424B5 Table of Contents Filed Pursuant to Rule 424(b)(5) Registration No. 333-284608 PROSPECTUS SUPPLEMENT (To Prospectus dated January 30, 2025) $850,000,000 Valero Energy Corporation 5.150% Senior Notes due 2036 This is an offering of $850,000,000 aggregate principal amount of our 5.150% Senior Notes due 2036 (the “notes”). The notes will mature on March 10, 2036. Interest on the notes will be p

VALERO ENERGY CORPORATION 5.150% Senior Notes due 2036

EX-4.2 Exhibit 4.2 VALERO ENERGY CORPORATION 5.150% Senior Notes due 2036 A single series of Securities is hereby established pursuant to Section 301 of the Indenture dated as of March 10, 2015 (the “Indenture”), between Valero Energy Corporation, a Delaware corporation (the “Company”), and U.S. Bank Trust Company, National Association, as successor in interest to U.S. Bank National Association, a

Security Type

Calculation of Filing Fee Tables S-3 VALERO ENERGY CORP/TX Table 1: Newly Registered and Carry Forward Securities ☐Not Applicable Security Type Security Class Title Fee Calculation or Carry Forward Rule Amount Registered Proposed Maximum Offering Price Per Unit Maximum Aggregate Offering Price Fee Rate Amount of Registration Fee Carry Forward Form Type Carry Forward File Number Carry Forward Initial Effective Date Filing Fee Previously Paid in Connection with Unsold Securities to be Carried Forward Newly Registered Securities Fees to be Paid 1 Debt 5.

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): March 5, 2026 VALERO ENERGY CORPO

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): March 5, 2026 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commission

VALERO ENERGY CORPORATION DEBT SECURITIES Underwriting Agreement

EX-1.1 Exhibit 1.1 Execution Version VALERO ENERGY CORPORATION DEBT SECURITIES Underwriting Agreement March 5, 2026 To the Representatives named in Schedule I hereto of the Underwriters named in Schedule II hereto Ladies and Gentlemen: Valero Energy Corporation, a Delaware corporation (the “Company”), proposes to issue and sell to the underwriters named in Schedule II hereto (the “Underwriters”),

Valero Energy Corporation Pricing Term Sheet $850,000,000 5.150% Senior Notes due 2036 Issuer: Valero Energy Corporation (the “Company”) Ratings*: Baa2 (stable) (Moody’s) / BBB (stable) (S&P) / BBB (stable) (Fitch) Pricing Date: March 5, 2026 Settlem

FWP Free Writing Prospectus Filed Pursuant to Rule 433 Registration Statement No. 333-284608 March 5, 2026 Valero Energy Corporation Pricing Term Sheet $850,000,000 5.150% Senior Notes due 2036 Issuer: Valero Energy Corporation (the “Company”) Ratings*: Baa2 (stable) (Moody’s) / BBB (stable) (S&P) / BBB (stable) (Fitch) Pricing Date: March 5, 2026 Settlement Date: March 10, 2026 (T+3) Denomination

SUBJECT TO COMPLETION, DATED MARCH 5, 2026

424B5 Table of Contents The information in this preliminary prospectus supplement is not complete and may be changed.

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-K

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-K (Mark One) ☑ ANNUAL REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the fiscal year ended December 31, 2025 OR ☐ TRANSITION REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to Commission file number 001-13175 VALERO ENERGY C

CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002

Exhibit 31.01 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, R. Lane Riggs, certify that: 1.I have reviewed this annual report on Form 10-K of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances under

Subsidiaries of Valero Energy Corporation as of December 31, 2025

Exhibit 21.01 Subsidiaries of Valero Energy Corporation as of December 31, 2025 Name of Entity State of Incorporation/ Organization AIR BP-PBF DEL PERU SAC Peru BELFAST STORAGE LTD Northern Ireland CANADIAN ULTRAMAR COMPANY Nova Scotia COLONNADE INSURANCE COMPANY Texas DIAMOND ALTERNATIVE ENERGY, LLC Delaware DIAMOND ALTERNATIVE ENERGY OF CANADA INC. Canada DIAMOND GREEN DIESEL HOLDINGS LLC Delawa

Consent of Independent Registered Public Accounting Firm

Exhibit 23.01 Consent of Independent Registered Public Accounting Firm We consent to the incorporation by reference in the registration statements, as amended, on Form S-3ASR (Registration No. 333-284608) and Form S-8 (Registration Nos. 333-106620, 333-129032, 333-136333, 333-174721, 333-205756, 333-238071, and 333-257917) of our reports dated February 25, 2026, with respect to the consolidated fi

CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002

Exhibit 31.02 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Homer S. Bhullar, certify that: 1.I have reviewed this annual report on Form 10-K of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances und

CERTIFICATION PURSUANT TO 18 U.S.C. SECTION 1350, AS ADOPTED PURSUANT TO SECTION 906 OF THE SARBANES-OXLEY ACT OF 2002

Exhibit 32.01 CERTIFICATION PURSUANT TO 18 U.S.C. SECTION 1350, AS ADOPTED PURSUANT TO SECTION 906 OF THE SARBANES-OXLEY ACT OF 2002 In connection with the Annual Report of Valero Energy Corporation (the Company) on Form 10-K for the year ended December 31, 2025, as filed with the Securities and Exchange Commission on the date hereof (the Report), the undersigned hereby certifies, pursuant to 18 U

Valero Energy Reports 2025 Fourth Quarter and Full Year Results

Exhibit 99.01 Valero Energy Reports 2025 Fourth Quarter and Full Year Results •Reported net income attributable to Valero stockholders of $1.1 billion, or $3.73 per share, for the fourth quarter and $2.3 billion, or $7.57 per share, for the year •Reported adjusted net income attributable to Valero stockholders of $1.2 billion, or $3.82 per share, for the fourth quarter and $3.3 billion, or $10.61

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): January 29, 2026 VALERO ENERGY CO

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): January 29, 2026 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commiss

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): October 28, 2025 VALERO ENERGY CO

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): October 28, 2025 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commiss

Valero Energy Corporation Announces CFO Transition Jason Fraser to Retire as CFO December 31 Homer Bhullar to Assume CFO Position

EX-99.1 Exhibit 99.1 Valero Energy Corporation Announces CFO Transition Jason Fraser to Retire as CFO December 31 Homer Bhullar to Assume CFO Position SAN ANTONIO, October 29, 2025 – Valero Energy Corporation (NYSE: VLO, “Valero”) announced today that Homer Bhullar, who has served as Valero’s Vice President-Investor Relations and Finance since April 29, 2021, has been appointed by Valero’s Board o

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q (Mark One) ☑ QUARTERLY REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the quarterly period ended September 30, 2025 OR ☐ TRANSITION REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to Commission File Number 001-13175 VALERO

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal executive officer.

Exhibit 31.01 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, R. Lane Riggs, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances und

Valero Energy Reports Third Quarter 2025 Results

Exhibit 99.01 Valero Energy Reports Third Quarter 2025 Results •Reported net income attributable to Valero stockholders of $1.1 billion, or $3.53 per share •Reported adjusted net income attributable to Valero stockholders of $1.1 billion, or $3.66 per share •Returned $1.3 billion to stockholders through dividends and stock buybacks •The St. Charles FCC Unit optimization project is expected to begi

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal financial officer.

Exhibit 31.02 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Jason W. Fraser, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances u

Section 1350 Certifications (under Section 906 of the Sarbanes-Oxley Act of 2002).

Exhibit 32.01 CERTIFICATION PURSUANT TO 18 U.S.C. SECTION 1350, AS ADOPTED PURSUANT TO SECTION 906 OF THE SARBANES-OXLEY ACT OF 2002 In connection with the Quarterly Report of Valero Energy Corporation (the Company) on Form 10-Q for the quarter ended September 30, 2025, as filed with the Securities and Exchange Commission on the date hereof (the Report), the undersigned hereby certifies, pursuant

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): October 23, 2025 VALERO ENERGY CO

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): October 23, 2025 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commiss

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of Earliest Event Reported): October 16, 2025 VALERO ENERGY CO

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of Earliest Event Reported): October 16, 2025 VALERO ENERGY CORPORATION (Exact Name of Registrant as Specified in its Charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commiss

AMENDED AND RESTATED REVOLVING CREDIT AGREEMENT dated as of October 16, 2025, VALERO ENERGY CORPORATION, THE LENDERS PARTY HERETO JPMORGAN CHASE BANK, N.A., as Administrative Agent CITIBANK, N.A. MIZUHO BANK, LTD., as Co-Syndication Agents BANK OF AM

EX-10.1 Exhibit 10.1 EXECUTION VERSION AMENDED AND RESTATED REVOLVING CREDIT AGREEMENT dated as of October 16, 2025, among VALERO ENERGY CORPORATION, THE LENDERS PARTY HERETO and JPMORGAN CHASE BANK, N.A., as Administrative Agent CITIBANK, N.A. and MIZUHO BANK, LTD., as Co-Syndication Agents BANK OF AMERICA, N.A., MUFG BANK, LTD., THE BANK OF NOVA SCOTIA, HOUSTON BRANCH SUMITOMO MITSUI BANKING COR

Valero Energy Corporation Elects Robert L. Reymond to Board of Directors

EX-99.1 Exhibit 99.1 Valero Energy Corporation Elects Robert L. Reymond to Board of Directors SAN ANTONIO, September 19, 2025 – Valero Energy Corporation (NYSE: VLO, “Valero”) announced today that Robert L. Reymond has been elected as an independent director to Valero’s board of directors (the “Board”) and has joined the Board’s Nominating and Corporate Governance Committee, effective immediately.

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): September 18, 2025 VALERO ENERGY

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): September 18, 2025 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commi

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): July 24, 2025 VALERO ENERGY CORPO

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): July 24, 2025 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commission

Subsidiary Issuer of Guaranteed Securities.

Exhibit 22.01 Subsidiary Issuer of Guaranteed Securities As of June 30, 2025, Valero Energy Corporation (Parent Guarantor) was the sole guarantor of the following series of unsecured notes issued by Valero Energy Partners LP, a Delaware limited partnership and an indirect wholly owned subsidiary of Parent Guarantor, and co-issued by Valero Refining-Texas, L.P., a Texas limited partnership, The Pre

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal executive officer.

Exhibit 31.01 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, R. Lane Riggs, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances und

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal financial officer.

Exhibit 31.02 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Jason W. Fraser, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances u

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q (Mark One) ☑ QUARTERLY REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the quarterly period ended June 30, 2025 OR ☐ TRANSITION REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to Commission File Number 001-13175 VALERO ENER

Valero Energy Reports Second Quarter 2025 Results

Exhibit 99.01 Valero Energy Reports Second Quarter 2025 Results •Reported net income attributable to Valero stockholders of $714 million, or $2.28 per share •Repaid the outstanding principal balance of $251 million of 2.85% Senior Notes that matured in April •Declared a regular quarterly cash dividend on common stock of $1.13 per share on July 17 •Returned $695 million to stockholders through divi

Section 1350 Certifications (under Section 906 of the Sarbanes-Oxley Act of 2002).

Exhibit 32.01 CERTIFICATION PURSUANT TO 18 U.S.C. SECTION 1350, AS ADOPTED PURSUANT TO SECTION 906 OF THE SARBANES-OXLEY ACT OF 2002 In connection with the Quarterly Report of Valero Energy Corporation (the Company) on Form 10-Q for the quarter ended June 30, 2025, as filed with the Securities and Exchange Commission on the date hereof (the Report), the undersigned hereby certifies, pursuant to 18

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 11-K

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 11-K (Mark One) ☑ ANNUAL REPORT PURSUANT TO SECTION 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the fiscal year ended December 31, 2024 OR ☐ TRANSITION REPORT PURSUANT TO SECTION 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to Commission file number 001-13175 A. Full title of the plan a

Consent of Independent Registered Public Accounting Firm

Exhibit 23.01 Consent of Independent Registered Public Accounting Firm We consent to the incorporation by reference in the registration statement (No. 333-136333) on Form S-8 of our report dated June 20, 2025, with respect to the financial statements and the supplemental Schedule H, line 4i–Schedule of Assets (Held at End of Year) as of December 31, 2024 of the Premcor Retirement Savings Plan. /s/

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 11-K

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 11-K (Mark One) ☑ ANNUAL REPORT PURSUANT TO SECTION 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the fiscal year ended December 31, 2024 OR ☐ TRANSITION REPORT PURSUANT TO SECTION 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to Commission file number 001-13175 A. Full title of the plan a

Consent of Independent Registered Public Accounting Firm

Exhibit 23.01 Consent of Independent Registered Public Accounting Firm We consent to the incorporation by reference in the registration statement (No. 333-257917) on Form S-8 of our report dated June 20, 2025, with respect to the financial statements and the supplemental Schedule H, line 4i–Schedule of Assets (Held at End of Year) as of December 31, 2024 of the Valero Energy Corporation Thrift Pla

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): May 6, 2025 VALERO ENERGY CORPORA

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): May 6, 2025 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commission F

Financial Statements and Exhibits, Results of Operations and Financial Condition

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): April 24, 2025 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commissio

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q (Mark One) ☑ QUARTERLY REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the quarterly period ended March 31, 2025 OR ☐ TRANSITION REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to Commission File Number 001-13175 VALERO ENE

Second Supplemental Indenture, dated as of April 17, 2025, among Valero Energy Partners LP, as issuer; the co-issuers party thereto; Valero Energy Corporation, as parent guarantor; and U.S. Bank Trust Company, National Association, as successor in interest to U.S. Bank National Association, as trustee.

Exhibit 4.01 Execution Version SECOND SUPPLEMENTAL INDENTURE VALERO ENERGY PARTNERS LP, as Issuer VALERO REFINING-TEXAS, L.P., as Co-Issuer THE PREMCOR REFINING GROUP INC., as Co-Issuer VALERO REFINING – MERAUX LLC, as Co-Issuer VALERO REFINING NEW ORLEANS, L.L.C., as Co-Issuer DIAMOND SHAMROCK REFINING COMPANY, L.P., as Co-Issuer VALERO ENERGY CORPORATION, as Parent Guarantor AND U.S. BANK TRUST

Valero Energy Reports First Quarter 2025 Results

Exhibit 99.01 Valero Energy Reports First Quarter 2025 Results •Reported a net loss attributable to Valero stockholders of $595 million, or $1.90 per share •Reported adjusted net income attributable to Valero stockholders of $282 million, or $0.89 per share •Issued $650 million aggregate principal amount of 5.15% Senior Notes due 2030 in February for debt repayment and general corporate purposes •

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal financial officer.

Exhibit 31.02 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Jason W. Fraser, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances u

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal executive officer.

Exhibit 31.01 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, R. Lane Riggs, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances und

Section 1350 Certifications (under Section 906 of the Sarbanes-Oxley Act of 2002).

Exhibit 32.01 CERTIFICATION PURSUANT TO 18 U.S.C. SECTION 1350, AS ADOPTED PURSUANT TO SECTION 906 OF THE SARBANES-OXLEY ACT OF 2002 In connection with the Quarterly Report of Valero Energy Corporation (the Company) on Form 10-Q for the quarter ended March 31, 2025, as filed with the Securities and Exchange Commission on the date hereof (the Report), the undersigned hereby certifies, pursuant to 1

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 (Amendment No. )

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 (Amendment No. ) Filed by the Registrant ☒       Filed by a party other than the Registrant ☐ Check the appropriate box: ☐ Preliminary Proxy Statement ☐ Confidential, for Use of the Commission Only (as permitted by Rule 14a-6(e)(2)) ☐

Results of Operations and Financial Condition, Other Events

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): April 16, 2025 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commissio

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 (Amendment No. )

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 (Amendment No. ) Filed by the Registrant ☒ Filed by a party other than the Registrant ☐ Check the appropriate box: ☐ Preliminary Proxy Statement ☐ Confidential, for Use of the Commission Only (as permitted by Rule 14a-6(e)(2)) ☐ Defin

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): March 18, 2025 VALERO ENERGY CORP

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): March 18, 2025 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 1-13175 74-1828067 (State or other jurisdiction of incorporation) (Commission

ARS

Cautionary Statement This presentation contains forward-looking statements made by Valero Energy Corporation (“VLO” or “Valero”) within the meaning of federal securities laws. These statements discuss future expectations, contain projections of resul

EX-99.01 Exhibit 99.01 Leading Producer of Liquid Advancing the Future of Energy • With Capital Discipline, Innovation and Unmatched Execution Transportation Fuels C A P I TA L D I S C I P L I N E I N N O VAT I O N U N M ATC H E D E X E C U T I O N I N V E S T O R P R E S E N T A T I O N | M A R C H 2 0 2 5 Cautionary Statement This presentation contains forward-looking statements made by Valero E

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 (Amendment No. )

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 (Amendment No. ) Filed by the Registrant ☒ Filed by a party other than the Registrant ☐ Check the appropriate box: ☐ Preliminary Proxy Statement ☐ Confidential, for Use of the Commission Only (as permitted by Rule 14a-6(e)(2)) ☒ Defin

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal executive officer.

Exhibit 31.01 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, R. Lane Riggs, certify that: 1.I have reviewed this annual report on Form 10-K of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances under

Form of Amended and Restated Performance Share Agreement (2024 grant–first tranche)–incorporated by reference to Exhibit 10.17 to Valero’s annual report on Form 10-K for the year ended December 31, 2024 (SEC File No. 001-13175).

Exhibit 10.17 AMENDED AND RESTATED PERFORMANCE SHARE AGREEMENT This Amended and Restated Performance Share Agreement (the “Agreement”), by and between Valero Energy Corporation, a Delaware corporation (“Valero”), and , a participant (the “Participant”) in Valero’s 2020 Omnibus Stock Incentive Plan (as may be amended, the “Plan”), is entered into effective January 16, 2025, pursuant to and subject

Valero Energy Corporation subsidiaries.

Exhibit 21.01 Subsidiaries of Valero Energy Corporation as of December 31, 2024 Name of Entity State of Incorporation/ Organization AIR BP-PBF DEL PERU SAC Peru BELFAST STORAGE LTD Northern Ireland CANADIAN ULTRAMAR COMPANY Nova Scotia COLONNADE INSURANCE COMPANY Texas DIAMOND ALTERNATIVE ENERGY, LLC Delaware DIAMOND ALTERNATIVE ENERGY OF CANADA INC. Canada DIAMOND GREEN DIESEL HOLDINGS LLC Delawa

Section 1350 Certifications (under Section 906 of the Sarbanes-Oxley Act of 2002).

Exhibit 32.01 CERTIFICATION PURSUANT TO 18 U.S.C. SECTION 1350, AS ADOPTED PURSUANT TO SECTION 906 OF THE SARBANES-OXLEY ACT OF 2002 In connection with the Annual Report of Valero Energy Corporation (the Company) on Form 10-K for the year ended December 31, 2024, as filed with the Securities and Exchange Commission on the date hereof (the Report), the undersigned hereby certifies, pursuant to 18 U

Consent of KPMG LLP dated February 26, 2025.

Exhibit 23.01 Consent of Independent Registered Public Accounting Firm We consent to the incorporation by reference in the registration statements, as amended, on Form S-3ASR (Registration No. 333-284608) and Form S-8 (Registration Nos. 333-106620, 333-129032, 333-136333, 333-174721, 333-205756, 333-238071, and 333-257917) of our reports dated February 26, 2025, with respect to the consolidated fi

Form of Amended and Restated Performance Share Agreement (2023 grant–third tranche, 2024 grant–second and third tranches, and current)–incorporated by reference to Exhibit 10.18 to Valero’s annual report on Form 10-K for the year ended December 31, 2024 (SEC File No. 001-13175).

Exhibit 10.18 AMENDED AND RESTATED PERFORMANCE SHARE AGREEMENT This Amended and Restated Performance Share Agreement (the “Agreement”), by and between Valero Energy Corporation, a Delaware corporation (“Valero”), and , a participant (the “Participant”) in Valero’s 2020 Omnibus Stock Incentive Plan (as may be amended, the “Plan”), is entered into effective February 26, 2025, pursuant to and subject

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal financial officer.

Exhibit 31.02 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Jason W. Fraser, certify that: 1.I have reviewed this annual report on Form 10-K of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances unde

Securities Trading Policy.

Exhibit 19.01 Securities Trading Policy Policy No.: S-026 Approved Date: August 31, 2024 Policy Owner: Corporate Law Approved By: General Counsel 1. Purpose Valero encourages its Employees to have a direct interest in Valero’s success through ownership of Valero securities. All Employees, however, are responsible for their own conduct and are required to avoid any appearance that he or she trades

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-K

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-K (Mark One) ☑ ANNUAL REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the fiscal year ended December 31, 2024 OR ☐ TRANSITION REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to Commission file number 001-13175 VALERO ENERGY C

Form of the Senior Notes due 2030 (included in Exhibit 4.2 above).

Exhibit 4.2 VALERO ENERGY CORPORATION 5.150% Senior Notes due 2030 A single series of Securities is hereby established pursuant to Section 301 of the Indenture dated as of March 10, 2015 (the “Indenture”), between Valero Energy Corporation, a Delaware corporation (the “Company”), and U.S. Bank Trust Company, National Association, as successor in interest to U.S. Bank National Association, as Trust

CALCULATION OF FILING FEE TABLES Form S-3 (Form Type) Valero Energy Corporation (Exact Name of Registrant as Specified in its Charter) Table 1: Newly Registered and Carry Forward Securities

Exhibit 107 CALCULATION OF FILING FEE TABLES Form S-3 (Form Type) Valero Energy Corporation (Exact Name of Registrant as Specified in its Charter) Table 1: Newly Registered and Carry Forward Securities Security Type Security Class Title Fee Calculation or Carry Forward Rule Amount Registered Proposed Maximum Offering Price Per Unit Maximum Aggregate Offering Price Fee Rate Amount of Registration Fee Carry Forward Form Type Carry Forward File Number Carry Forward Initial Effective Date Filing Fee Previously Paid In Connection with Unsold Securities to be Carried Forward Newly Registered Securities Fees to Be Paid (1) Debt 5.

Underwriting Agreement dated February 4, 2025 among the Company and Citigroup Global Markets Inc., BofA Securities, Inc., J.P. Morgan Securities LLC and Mizuho Securities USA LLC, as representatives of the several underwriters named therein.

Exhibit 1.1 VALERO ENERGY CORPORATION DEBT SECURITIES Underwriting Agreement February 4, 2025 To the Representatives named in Schedule I hereto of the Underwriters named in Schedule II hereto Ladies and Gentlemen: Valero Energy Corporation, a Delaware corporation (the “Company”), proposes to issue and sell to the underwriters named in Schedule II hereto (the “Underwriters”), for whom you are actin

Current Report

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): February 4, 2025 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commiss

$650,000,000 Valero Energy Corporation 5.150% Senior Notes due 2030

Filed Pursuant to Rule 424(b)(5) Registration No. 333-284608 PROSPECTUS SUPPLEMENT (To Prospectus dated January 30, 2025) $650,000,000 Valero Energy Corporation 5.150% Senior Notes due 2030 This is an offering of $650,000,000 aggregate principal amount of our 5.150% Senior Notes due 2030 (the “notes”). The notes will mature on February 15, 2030. Interest on the notes will be payable semi-annually

SUBJECT TO COMPLETION, DATED FEBRUARY 4, 2025

Table of Contents Filed Pursuant to Rule 424(b)(5) Registration No. 333-284608 The information in this preliminary prospectus supplement is not complete and may be changed. This preliminary prospectus supplement and the accompanying prospectus are not an offer to sell these securities and are not soliciting an offer to buy these securities in any jurisdiction where the offer or sale is not permitt

Valero Energy Corporation Pricing Term Sheet $650,000,000 5.150% Senior Notes due 2030 Issuer: Valero Energy Corporation (the “Company”) Ratings*: Baa2 (stable) (Moody’s) / BBB (stable) (S&P) / BBB (stable) (Fitch) Pricing Date: February 4, 2025 Sett

Free Writing Prospectus Filed Pursuant to Rule 433 Registration Statement No. 333-284608 February 4, 2025 Valero Energy Corporation Pricing Term Sheet $650,000,000 5.150% Senior Notes due 2030 Issuer: Valero Energy Corporation (the “Company”) Ratings*: Baa2 (stable) (Moody’s) / BBB (stable) (S&P) / BBB (stable) (Fitch) Pricing Date: February 4, 2025 Settlement Date: February 7, 2025 (T+3) Denomina

Filing Fee Table.

Exhibit 107 CALCULATION OF FILING FEE TABLES Form S-3 (Form Type) Valero Energy Corporation (Exact Name of Registrant as Specified in its Charter) Table 1: Newly Registered and Carry Forward Securities Security  Type Security Class Title Fee Calculation  or Carry Forward Rule Amount Registered Proposed Maximum  Offering Price Per Unit Maximum Aggregate  Offering Price Fee Rate Amount of Registrati

Statement of Eligibility and Qualification under the Trust Indenture Act of 1939 of U.S. Bank Trust Company, National Association, as successor in interest to U.S. Bank National Association, as trustee, on Form T-1.

Exhibit 25.1 SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM T-1 STATEMENT OF ELIGIBILITY UNDER THE TRUST INDENTURE ACT OF 1939 OF A CORPORATION DESIGNATED TO ACT AS TRUSTEE ☐ Check if an Application to Determine Eligibility of a Trustee Pursuant to Section 305(b)(2) U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION (Exact name of Trustee as specified in its charter) 91-1821036 I.R.S. E

Financial Statements and Exhibits, Results of Operations and Financial Condition

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): January 30, 2025 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commiss

Valero Energy Reports 2024 Fourth Quarter and Full Year Results

Exhibit 99.01 Valero Energy Reports 2024 Fourth Quarter and Full Year Results •Reported net income attributable to Valero stockholders of $281 million, or $0.88 per share, for the fourth quarter and $2.8 billion, or $8.58 per share, for the year •Reported adjusted net income attributable to Valero stockholders of $207 million, or $0.64 per share, for the fourth quarter and $2.7 billion, or $8.48 p

As filed with the Securities and Exchange Commission on January 30, 2025

As filed with the Securities and Exchange Commission on January 30, 2025 Registration No.

Current Report

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): January 30, 2025 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commiss

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal financial officer.

Exhibit 31.02 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Jason W. Fraser, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances u

Section 1350 Certifications (under Section 906 of the Sarbanes-Oxley Act of 2002).

Exhibit 32.01 CERTIFICATION PURSUANT TO 18 U.S.C. SECTION 1350, AS ADOPTED PURSUANT TO SECTION 906 OF THE SARBANES-OXLEY ACT OF 2002 In connection with the Quarterly Report of Valero Energy Corporation (the Company) on Form 10-Q for the quarter ended September 30, 2024, as filed with the Securities and Exchange Commission on the date hereof (the Report), the undersigned hereby certifies, pursuant

Current Report

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): October 29, 2024 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 1-13175 74-1828067 (State or other jurisdiction of incorporation) (Commissio

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal executive officer.

Exhibit 31.01 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, R. Lane Riggs, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances und

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q (Mark One) ☑ QUARTERLY REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the quarterly period ended September 30, 2024 OR ☐ TRANSITION REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to Commission File Number 001-13175 VALERO

Financial Statements and Exhibits, Results of Operations and Financial Condition

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): October 24, 2024 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commiss

Valero Energy Reports Third Quarter 2024 Results

Exhibit 99.01 Valero Energy Reports Third Quarter 2024 Results •Reported net income attributable to Valero stockholders of $364 million, or $1.14 per share •Returned $907 million to stockholders through dividends and stock buybacks •Successfully completed the Diamond Green Diesel (DGD) Port Arthur Sustainable Aviation Fuel (SAF) project in October SAN ANTONIO, October 24, 2024 – Valero Energy Corp

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal executive officer.

Exhibit 31.01 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, R. Lane Riggs, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances und

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q (Mark One) ☑ QUARTERLY REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the quarterly period ended June 30, 2024 OR ☐ TRANSITION REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to Commission File Number 001-13175 VALERO ENER

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): July 25, 2024 VALERO ENERGY CORPO

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): July 25, 2024 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commission

Valero Energy Reports Second Quarter 2024 Results

Exhibit 99.01 Valero Energy Reports Second Quarter 2024 Results •Reported net income attributable to Valero stockholders of $880 million, or $2.71 per share •Declared a regular quarterly cash dividend on common stock of $1.07 per share on July 18 •Returned $1.4 billion to stockholders through dividends and stock buybacks SAN ANTONIO, July 25, 2024 – Valero Energy Corporation (NYSE: VLO, “Valero”)

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal financial officer.

Exhibit 31.02 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Jason W. Fraser, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances u

Section 1350 Certifications (under Section 906 of the Sarbanes-Oxley Act of 2002).

Exhibit 32.01 CERTIFICATION PURSUANT TO 18 U.S.C. SECTION 1350, AS ADOPTED PURSUANT TO SECTION 906 OF THE SARBANES-OXLEY ACT OF 2002 In connection with the Quarterly Report of Valero Energy Corporation (the Company) on Form 10-Q for the quarter ended June 30, 2024, as filed with the Securities and Exchange Commission on the date hereof (the Report), the undersigned hereby certifies, pursuant to 18

Consent of Independent Registered Public Accounting Firm

Exhibit 23.01 Consent of Independent Registered Public Accounting Firm We consent to the incorporation by reference in the registration statement (No. 333-257917) on Form S-8 of our report dated June 21, 2024, with respect to the financial statements and the supplemental Schedule H, line 4i–Schedule of Assets (Held at End of Year) as of December 31, 2023 of the Valero Energy Corporation Thrift Pla

Consent of Independent Registered Public Accounting Firm

Exhibit 23.01 Consent of Independent Registered Public Accounting Firm We consent to the incorporation by reference in the registration statement (No. 333-136333) on Form S-8 of our report dated June 21, 2024, with respect to the financial statements and the supplemental Schedule H, line 4i–Schedule of Assets (Held at End of Year) as of December 31, 2023 of the Premcor Retirement Savings Plan. /s/

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 11-K ANNUAL REPORT PURSUANT TO SECTION 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the fiscal year ended December 31, 2023 Commission File Number 001-13175 PREMCOR RETI

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 11-K ANNUAL REPORT PURSUANT TO SECTION 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the fiscal year ended December 31, 2023 Commission File Number 001-13175 PREMCOR RETIREMENT SAVINGS PLAN VALERO ENERGY CORPORATION One Valero Way San Antonio, Texas 78249 PREMCOR RETIREMENT SAVINGS PLAN Table of Contents Page Report of

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 11-K ANNUAL REPORT PURSUANT TO SECTION 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the fiscal year ended December 31, 2023 Commission File Number 001-13175 VALERO ENERG

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 11-K ANNUAL REPORT PURSUANT TO SECTION 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the fiscal year ended December 31, 2023 Commission File Number 001-13175 VALERO ENERGY CORPORATION THRIFT PLAN VALERO ENERGY CORPORATION One Valero Way San Antonio, Texas 78249 VALERO ENERGY CORPORATION THRIFT PLAN Table of Contents Pa

LETTER

United States securities and exchange commission logo June 20, 2024 Jason W. Fraser Chief Financial Officer Valero Energy Corporation One Valero Way San Antonio, Texas 78249 Re: Valero Energy Corporation Form 10-K for the Fiscal Year ended December 31, 2023 Filed February 22, 2024 File No. 001-13175 Dear Jason W. Fraser: We have completed our review of your filing. We remind you that the company a

One Valero Way • San Antonio, Texas 78249-1616 Post Office Box 696000 • San Antonio, Texas 78269-6000 • Telephone (210) 345-2280

Jason W. Fraser Executive Vice President and Chief Financial Officer VIA EDGAR TRANSMISSION June 17, 2024 U.S. Securities and Exchange Commission Division of Corporation Finance Office of Energy & Transportation 100 F Street, NE Washington, DC 20549 Attention: Gus Rodriguez and John Cannarella Re: Valero Energy Corporation Form 10-K for the Fiscal Year ended December 31, 2023 Filed February 22, 20

LETTER

United States securities and exchange commission logo June 4, 2024 Jason W. Fraser Chief Financial Officer Valero Energy Corporation One Valero Way San Antonio, Texas 78249 Re: Valero Energy Corporation Form 10-K for the Fiscal Year ended December 31, 2023 Filed February 22, 2024 File No. 001-13175 Dear Jason W. Fraser: We have limited our review of your filing to the financial statements and rela

Form of Stock Unit Award Agreement (with one-year hold provision).

Exhibit 10.01 STOCK UNIT AWARD AGREEMENT (with one year holding period) This Stock Unit Award Agreement (“Agreement”), dated as of May 15, 2024 (the “Grant Date”), is between Valero Energy Corporation, a Delaware corporation (“Valero”), and «FirstName» «LastName», a Non-Employee Director of the Board of Directors of Valero (“Director”), who agree as follows: 1. Grant of Stock Units. Pursuant to th

Current Report

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): May 15, 2024 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commission

Cautionary Statement This presentation contains forward-looking statements made by Valero Energy Corporation (“VLO” or “Valero”) within the meaning of federal securities laws. These statements discuss future expectations, contain projections of resul

EX-99.1 Exhibit 99.1 Leading Producer of Liquid Advancing the Future of Energy • With Capital Discipline, Innovation and Unmatched Execution Transportation Fuels C A P I TA L D I S C I P L I N E I N N O VAT I O N U N M ATC H E D E X E C U T I O N I N V E S T O R P R E S E N T A T I O N | M A Y 2 0 2 4 Cautionary Statement This presentation contains forward-looking statements made by Valero Energy

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): May 1, 2024 VALERO ENERGY CORPORA

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): May 1, 2024 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commission F

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): April 25, 2024 VALERO ENERGY CORP

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): April 25, 2024 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commissio

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q (Mark One) ☑ QUARTERLY REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the quarterly period ended March 31, 2024 OR ☐ TRANSITION REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to Commission File Number 001-13175 VALERO ENE

Valero Energy Reports First Quarter 2024 Results

Exhibit 99.01 Valero Energy Reports First Quarter 2024 Results •Reported net income attributable to Valero stockholders of $1.2 billion, or $3.75 per share •Reported adjusted net income attributable to Valero stockholders of $1.3 billion, or $3.82 per share •Repaid the $167 million outstanding principal balance of its 1.200% Senior Notes that matured on March 15 •Declared a regular quarterly cash

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal executive officer.

Exhibit 31.01 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, R. Lane Riggs, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances und

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal financial officer.

Exhibit 31.02 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Jason W. Fraser, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances u

Section 1350 Certifications (under Section 906 of the Sarbanes-Oxley Act of 2002).

Exhibit 32.01 CERTIFICATION PURSUANT TO 18 U.S.C. SECTION 1350, AS ADOPTED PURSUANT TO SECTION 906 OF THE SARBANES-OXLEY ACT OF 2002 In connection with the Quarterly Report of Valero Energy Corporation (the Company) on Form 10-Q for the quarter ended March 31, 2024, as filed with the Securities and Exchange Commission on the date hereof (the Report), the undersigned hereby certifies, pursuant to 1

ARS

2024 Notice of Annual Meeting of Stockholders PROXY STATEMENT & ANNUAL REPORT ON FORM 10-K*EJ?9;
E<

DDK7B
);;J?D=
E<
/JE9A>EB:;HI 3DA

=JJQ=H
IAAPEJC
KB
OPK?GDKH@ANO
KB
5=HANK
$JANCU
"KNLKN =PEKJ
EO
O?DA@QHA@
PK
>A
DAH@
EJ
=
RENPQ=H
BKNI=P
=O
BKHHKSO )!!0%*#
0!

0%)! )!!0%*#
/%0! .

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 (Amendment No. )

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 (Amendment No. ) Filed by the Registrant ☒ Filed by a party other than the Registrant ☐ Check the appropriate box: ☐ Preliminary Proxy Statement ☐ Confidential, for Use of the Commission Only (as permitted by Rule 14a-6(e)(2)) ☒ Defin

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 (Amendment No.)

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 (Amendment No.) Filed by the Registrant ☒ Filed by a party other than the Registrant ☐ Check the appropriate box: ☐ Preliminary Proxy Statement ☐ Confidential, for Use of the Commission Only (as permitted by Rule 14a-6(e)(2)) ☐ Defini

Section 1350 Certifications (under Section 906 of the Sarbanes-Oxley Act of 2002).

Exhibit 32.01 CERTIFICATION PURSUANT TO 18 U.S.C. SECTION 1350, AS ADOPTED PURSUANT TO SECTION 906 OF THE SARBANES-OXLEY ACT OF 2002 In connection with the Annual Report of Valero Energy Corporation (the Company) on Form 10-K for the year ended December 31, 2023, as filed with the Securities and Exchange Commission on the date hereof (the Report), the undersigned hereby certifies, pursuant to 18 U

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal executive officer.

Exhibit 31.01 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, R. Lane Riggs, certify that: 1.I have reviewed this annual report on Form 10-K of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances under

Valero Energy Corporation subsidiaries.

Exhibit 21.01 Subsidiaries of Valero Energy Corporation as of December 31, 2023 Name of Entity State of Incorporation/ Organization AIR BP-PBF DEL PERU SAC Peru BELFAST STORAGE LTD Northern Ireland CANADIAN ULTRAMAR COMPANY Nova Scotia COLONNADE INSURANCE COMPANY Texas DIAMOND ALTERNATIVE ENERGY, LLC Delaware DIAMOND ALTERNATIVE ENERGY OF CANADA INC. Canada DIAMOND GREEN DIESEL HOLDINGS LLC Delawa

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-K

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-K (Mark One) ☑ ANNUAL REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the fiscal year ended December 31, 2023 OR ☐ TRANSITION REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to Commission file number 001-13175 VALERO ENERGY C

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal financial officer.

Exhibit 31.02 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Jason W. Fraser, certify that: 1.I have reviewed this annual report on Form 10-K of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances unde

Consent of KPMG LLP dated February 22, 2024.

Exhibit 23.01 Consent of Independent Registered Public Accounting Firm We consent to the incorporation by reference in the registration statements, as amended, on Form S-3ASR (Registration No. 333-261165) and Form S-8 (Registration Nos. 333-106620, 333-129032, 333-136333, 333-174721, 333-205756, 333-238071, and 333-257917) of our reports dated February 22, 2024, with respect to the consolidated fi

Executive Compensation Clawback Policy.

Exhibit 97.01 VALERO ENERGY CORPORATION EXECUTIVE COMPENSATION CLAWBACK POLICY Valero Energy Corporation (the “Company”) has long viewed executive compensation clawback policies as an important risk mitigation tool and an element of compensation governance best practices. Since 2009, the Company has maintained a clawback policy titled Policy on Executive Compensation in Restatement Situations (the

VLO / Valero Energy Corporation / VANGUARD GROUP INC - SCHEDULE 13G/A Passive Investment

SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 Schedule 13G Under the Securities Exchange Act of 1934 (Amendment No.: 10)* Name of issuer: Valero Energy Corp Title of Class of Securities: Common Stock CUSIP Number: 91913Y100 Date of Event Which Requires Filing of this Statement: December 29, 2023 Check the appropriate box to designate the rule pursuant to which this Schedule is filed: ☒

VLO / Valero Energy Corporation / STATE STREET CORP Passive Investment

SC 13G/A 1 ValeroEnergyCorp.txt UNITED STATES SECURITIES AND EXCHANGE COMMISSION WASHINGTON, D.C. 20549 SCHEDULE 13G UNDER THE SECURITIES EXCHANGE ACT OF 1934 AMENDED FILING VALERO ENERGY CORP (NAME OF ISSUER) COMMON STOCK (TITLE OF CLASS OF SECURITIES) 91913Y100 (CUSIP NUMBER) 12/31/2023 (DATE OF EVENT WHICH REQUIRES FILING OF THIS STATEMENT) CHECK THE APPROPRIATE BOX TO DESIGNATE THE RULE PURSUA

VLO / Valero Energy Corporation / BlackRock Inc. Passive Investment

SC 13G/A 1 us91913y1001012524.txt us91913y1001012524.txt SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 13G Under the Securities Exchange Act of 1934 (Amendment No: 14) VALERO ENERGY CORP - (Name of Issuer) Common Stock - (Title of Class of Securities) 91913Y100 - (CUSIP Number) December 31, 2023 - (Date of Event Which Requires Filing of this Statement) Check the appropriate bo

Valero Energy Reports 2023 Fourth Quarter and Full Year Results

Exhibit 99.01 Valero Energy Reports 2023 Fourth Quarter and Full Year Results •Reported net income attributable to Valero stockholders of $1.2 billion, or $3.55 per share, for the fourth quarter and $8.8 billion, or $24.92 per share, for the year •Reported adjusted net income attributable to Valero stockholders of $8.8 billion, or $24.90 per share, for the year •Returned $1.3 billion to stockholde

Financial Statements and Exhibits, Results of Operations and Financial Condition

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): January 25, 2024 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commiss

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): November 6, 2023 VALERO ENERGY CO

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): November 6, 2023 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 1-13175 74-1828067 (State or other jurisdiction of incorporation) (Commissio

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal financial officer.

Exhibit 31.02 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Jason W. Fraser, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances u

Valero Energy Reports Third Quarter 2023 Results

Exhibit 99.01 Valero Energy Reports Third Quarter 2023 Results •Reported net income attributable to Valero stockholders of $2.6 billion, or $7.49 per share •Returned $2.2 billion to stockholders through dividends and stock buybacks SAN ANTONIO, October 26, 2023 – Valero Energy Corporation (NYSE: VLO, “Valero”) today reported net income attributable to Valero stockholders of $2.6 billion, or $7.49

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal executive officer.

Exhibit 31.01 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, R. Lane Riggs, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances und

Section 1350 Certifications (under Section 906 of the Sarbanes-Oxley Act of 2002).

Exhibit 32.01 CERTIFICATION PURSUANT TO 18 U.S.C. SECTION 1350, AS ADOPTED PURSUANT TO SECTION 906 OF THE SARBANES-OXLEY ACT OF 2002 In connection with the Quarterly Report of Valero Energy Corporation (the Company) on Form 10-Q for the quarter ended September 30, 2023, as filed with the Securities and Exchange Commission on the date hereof (the Report), the undersigned hereby certifies, pursuant

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q (Mark One) ☑ QUARTERLY REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the quarterly period ended September 30, 2023 OR ☐ TRANSITION REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to Commission File Number 001-13175 VALERO

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): October 26, 2023 VALERO ENERGY CO

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): October 26, 2023 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commiss

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): September 11, 2023 VALERO ENERGY

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): September 11, 2023 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 1-13175 74-1828067 (State or other jurisdiction of incorporation) (Commiss

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal executive officer.

Exhibit 31.01 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, R. Lane Riggs, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances und

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): July 27, 2023 VALERO ENERGY CORPO

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): July 27, 2023 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commission

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q (Mark One) ☑ QUARTERLY REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the quarterly period ended June 30, 2023 OR ☐ TRANSITION REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to Commission File Number 001-13175 VALERO ENER

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal financial officer.

Exhibit 31.02 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Jason W. Fraser, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances u

Section 1350 Certifications (under Section 906 of the Sarbanes-Oxley Act of 2002).

Exhibit 32.01 CERTIFICATION PURSUANT TO 18 U.S.C. SECTION 1350, AS ADOPTED PURSUANT TO SECTION 906 OF THE SARBANES-OXLEY ACT OF 2002 In connection with the Quarterly Report of Valero Energy Corporation (the Company) on Form 10-Q for the quarter ended June 30, 2023, as filed with the Securities and Exchange Commission on the date hereof (the Report), the undersigned hereby certifies, pursuant to 18

Valero Energy Corporation Supplemental Executive Retirement Plan, as amended and restated effective July 1, 2023–incorporated by reference to Exhibit 10.01 to Valero’s quarterly report on Form 10-Q for the quarter ended June 30, 2023 (SEC File No. 001-13175).

Exhibit 10.01 VALERO ENERGY CORPORATION SUPPLEMENTAL EXECUTIVE RETIREMENT PLAN (AS AMENDED AND RESTATED EFFECTIVE JULY 1, 2023) VALERO ENERGY CORPORATION SUPPLEMENTAL EXECUTIVE RETIREMENT PLAN TABLE OF CONTENTS Page ARTICLE I DEFINITIONS 1 1.1 Accrued Benefit 1 1.2 Actuarial Equivalent or Actuarially Equivalent Basis 1 1.3 Beneficiary 2 1.4 Board of Directors 2 1.5 Change in Control 2 1.6 Code 2 1

Valero Energy Reports Second Quarter 2023 Results

Exhibit 99.01 Valero Energy Reports Second Quarter 2023 Results •Reported net income attributable to Valero stockholders of $1.9 billion, or $5.40 per share •Returned over $1.3 billion to stockholders through dividends and stock buybacks •Declared a regular quarterly cash dividend on common stock of $1.02 per share SAN ANTONIO, July 27, 2023 – Valero Energy Corporation (NYSE: VLO, “Valero”) today

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): July 20, 2023 VALERO ENERGY CORPO

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): July 20, 2023 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 1-13175 74-1828067 (State or other jurisdiction of incorporation) (Commission F

Consent of Independent Registered Public Accounting Firm

Exhibit 23.01 Consent of Independent Registered Public Accounting Firm We consent to the incorporation by reference in the registration statement (No. 333-257917) on Form S-8 of our report dated June 23, 2023, with respect to the financial statements and the supplemental Schedule H, Line 4i–Schedule of Assets (Held at End of Year) as of December 31, 2022 of the Valero Energy Corporation Thrift Pla

Consent of Independent Registered Public Accounting Firm

Exhibit 23.01 Consent of Independent Registered Public Accounting Firm We consent to the incorporation by reference in the registration statement (No. 333-136333) on Form S-8 of our report dated June 23, 2023, with respect to the financial statements and the supplemental Schedule H, Line 4i–Schedule of Assets (Held at End of Year) as of December 31, 2022 of the Premcor Retirement Savings Plan. /s/

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 11-K ANNUAL REPORT PURSUANT TO SECTION 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the fiscal year ended December 31, 2022 Commission File Number 001-13175 VALERO ENERG

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 11-K ANNUAL REPORT PURSUANT TO SECTION 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the fiscal year ended December 31, 2022 Commission File Number 001-13175 VALERO ENERGY CORPORATION THRIFT PLAN VALERO ENERGY CORPORATION One Valero Way San Antonio, Texas 78249 VALERO ENERGY CORPORATION THRIFT PLAN Table of Contents Pa

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 11-K ANNUAL REPORT PURSUANT TO SECTION 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the fiscal year ended December 31, 2022 Commission File Number 001-13175 PREMCOR RETI

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 11-K ANNUAL REPORT PURSUANT TO SECTION 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the fiscal year ended December 31, 2022 Commission File Number 001-13175 PREMCOR RETIREMENT SAVINGS PLAN VALERO ENERGY CORPORATION One Valero Way San Antonio, Texas 78249 PREMCOR RETIREMENT SAVINGS PLAN Table of Contents Page Report of

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): May 8, 2023 VALERO ENERGY CORPORA

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): May 8, 2023 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 1-13175 74-1828067 (State or other jurisdiction of incorporation) (Commission Fil

Miller/Howard Investments’ Memo in Support of Proposal No. 5 – Challenging the Representations in Valero Energy’s Recent Filing

Miller/Howard Investments’ Memo in Support of Proposal No. 5 – Challenging the Representations in Valero Energy’s Recent Filing As long-term investors in Valero Energy (“Valero” or “the company”), Miller/Howard Investments, Inc. is concerned that the company’s lack of strong and comprehensive greenhouse gas targets—in contrast to peers like Phillips 66 and Marathon Petroleum Corporation—raises que

We are not asking for authority to vote your proxy and no proxy cards will be accepted. Please vote your proxy according to the instructions in Valero’s proxy statement.

Notice of Exempt Solicitation NAME OF REGISTRANT: Valero Energy Corporation NAME OF PERSON RELYING ON EXEMPTION: Service Employees International Union Pension Plans Master Trust ADDRESS OF PERSON RELYING ON EXEMPTION: 1800 Massachusetts Avenue, NW Washington, DC 20036 Written materials are submitted pursuant to Rule 14a-6(g)(1) promulgated under the Securities Exchange Act of 1934.

Form of Amended and Restated Performance Share Agreement (2022 grant–second and third tranches).

Exhibit 10.02 AMENDED AND RESTATED PERFORMANCE SHARE AGREEMENT This Amended and Restated Performance Share Agreement (the “Agreement”), by and between Valero Energy Corporation, a Delaware corporation (“Valero”), and, a participant (the “Participant”) in Valero’s 2020 Omnibus Stock Incentive Plan (as may be amended, the “Plan”), is entered into effective February 23, 2023 pursuant to and subject t

Form of Aircraft Time Sharing Agreement–incorporated by reference to Exhibit 10.04 to Valero’s quarterly report on Form 10-Q for the quarter ended March 31, 2023 (SEC File No. 001-13175).

Exhibit 10.04 AIRCRAFT TIME SHARING AGREEMENT This AIRCRAFT TIME SHARING AGREEMENT (the “Agreement”) is entered into on [Month] [Day], [Year], by and between Valero Services, Inc., a Delaware corporation (the “Company”), and [Executive], an individual (the “Executive”), and shall be effective commencing [Month] [Day], [Year] (the “Effective Date”). W I T N E S E T H: WHEREAS, the Company owns, lea

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal financial officer.

Exhibit 31.02 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Jason W. Fraser, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances u

Form of Amended and Restated Performance Share Agreement (2021 grant–third tranche).

Exhibit 10.01 AMENDED AND RESTATED PERFORMANCE SHARE AGREEMENT This Amended and Restated Performance Share Agreement (the “Agreement”), by and between Valero Energy Corporation, a Delaware corporation (“Valero”), and , a participant (the “Participant”) in Valero’s 2020 Omnibus Stock Incentive Plan (as may be amended, the “Plan”), is entered into effective February 23, 2023 pursuant to and subject

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q (Mark One) ☑ QUARTERLY REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the quarterly period ended March 31, 2023 OR ☐ TRANSITION REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to Commission File Number 001-13175 VALERO ENE

Section 1350 Certifications (under Section 906 of the Sarbanes-Oxley Act of 2002).

Exhibit 32.01 CERTIFICATION PURSUANT TO 18 U.S.C. SECTION 1350, AS ADOPTED PURSUANT TO SECTION 906 OF THE SARBANES-OXLEY ACT OF 2002 In connection with the Quarterly Report of Valero Energy Corporation (the Company) on Form 10-Q for the quarter ended March 31, 2023, as filed with the Securities and Exchange Commission on the date hereof (the Report), the undersigned hereby certifies, pursuant to 1

Form of Performance Share Agreement (2023 grant and current).

Exhibit 10.03 PERFORMANCE SHARE AGREEMENT This Performance Share Agreement (the “Agreement”), by and between Valero Energy Corporation, a Delaware corporation (“Valero”), and, a participant (the “Participant”) in Valero’s 2020 Omnibus Stock Incentive Plan (as may be amended, the “Plan”), is entered into pursuant to and subject to the provisions of the Plan, to set forth the terms and conditions of

(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal execut

Exhibit 31.01 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Joseph W. Gorder, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances

SEC filing,

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 Filed by the Registrant ☒ Filed by a party other than the Registrant ☐ Check the appropriate box: ☐ Preliminary Proxy Statement ☐ Confidential, for Use of the Commission Only (as permitted by Rule 14a-6(e)(2)) ☐ Definitive Proxy State

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): April 27, 2023 VALERO ENERGY CORP

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): April 27, 2023 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commissio

Valero Energy Reports First Quarter 2023 Results

Exhibit 99.01 Valero Energy Reports First Quarter 2023 Results •Reported net income attributable to Valero stockholders of $3.1 billion, or $8.29 per share •Reported adjusted net income attributable to Valero stockholders of $3.1 billion, or $8.27 per share •Reduced debt by $199 million •Returned over $1.8 billion to stockholders through dividends and stock buybacks and declared a regular quarterl

exempt solicitation,

United States Securities and Exchange Commission Washington, D.C. 20549 NOTICE OF EXEMPT SOLICITATION Pursuant to Rule 14a-103 Name of the Registrant: Valero Energy Corporation Name of persons relying on exemption: Mercy Investment Services, Inc. Address of persons relying on exemption: 2039 North Geyer Road, Saint Louis, MO 63131 Written materials are submitted pursuant to Rule 14a-6(g) (1) promu

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 Filed by the Registrant ☒ Filed by a party other than the Registrant ☐ Check the appropriate box: ☐ Preliminary Proxy Statement ☐ Confidential, for Use of the Commission Only (as permitted by Rule 14a-6(e)(2)) ☐ Definitive Proxy State

Notice Of Exempt Solicitation: (VOLUNTARY SUBMISSION)

Notice Of Exempt Solicitation: (VOLUNTARY SUBMISSION) NAME OF REGISTRANT: Valero Energy Corp NAME OF PERSON RELYING ON EXEMPTION: Majority Action ADDRESS OF PERSON RELYING ON EXEMPTION: PO Box 4831, Silver Spring, MD 20914 Written materials are submitted pursuant to Rule 14a-6(g)(1) promulgated under the Securities Exchange Act of 1934.

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 Filed by the Registrant ☒ Filed by a party other than the Registrant ☐ Check the appropriate box: ☐ Preliminary Proxy Statement ☐ Confidential, for Use of the Commission Only (as permitted by Rule 14a-6(e)(2)) ☐ Definitive Proxy State

Valero Energy Corporation Vote Yes: Proposal #5 Annual Meeting: May 5, 2023

Valero Energy Corporation Vote Yes: Proposal #5 Annual Meeting: May 5, 2023 CONTACT: Mary Minette, Mercy Investment Services | mminette@mercyinvestments.

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 Filed by the Registrant ☒ Filed by a party other than the Registrant ☐ Check the appropriate box: ☐ Preliminary Proxy Statement ☐ Confidential, for Use of the Commission Only (as permitted by Rule 14a-6(e)(2)) ☒ Definitive Proxy State

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 Filed by the Registrant ☒ Filed by a party other than the Registrant ☐ Check the appropriate box: ☐ Preliminary Proxy Statement ☐ Confidential, for Use of the Commission Only (as permitted by Rule 14a-6(e)(2)) ☐ Definitive Proxy State

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-K

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-K (Mark One) ☑ ANNUAL REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the fiscal year ended December 31, 2022 OR ☐ TRANSITION REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to Commission file number 001-13175 VALERO ENERGY C

Valero Energy Corporation subsidiaries.

Exhibit 21.01 Subsidiaries of Valero Energy Corporation as of February 14, 2023 Name of Entity State of Incorporation/ Organization AIR BP-PBF DEL PERU SAC Peru BELFAST STORAGE LTD Northern Ireland CANADIAN ULTRAMAR COMPANY Nova Scotia COLONNADE INSURANCE COMPANY Texas DIAMOND ALTERNATIVE ENERGY, LLC Delaware DIAMOND ALTERNATIVE ENERGY OF CANADA INC. Canada DIAMOND GREEN DIESEL HOLDINGS LLC Delawa

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal executive officer.

Exhibit 31.01 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Joseph W. Gorder, certify that: 1.I have reviewed this annual report on Form 10-K of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances und

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal financial officer.

Exhibit 31.02 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Jason W. Fraser, certify that: 1.I have reviewed this annual report on Form 10-K of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances unde

Section 1350 Certifications (under Section 906 of the Sarbanes-Oxley Act of 2002).

Exhibit 32.01 CERTIFICATION PURSUANT TO 18 U.S.C. SECTION 1350, AS ADOPTED PURSUANT TO SECTION 906 OF THE SARBANES-OXLEY ACT OF 2002 In connection with the Annual Report of Valero Energy Corporation (the Company) on Form 10-K for the year ended December 31, 2022, as filed with the Securities and Exchange Commission on the date hereof (the Report), the undersigned hereby certifies, pursuant to 18 U

Consent of KPMG LLP dated February 23, 2023.

Exhibit 23.01 Consent of Independent Registered Public Accounting Firm We consent to the incorporation by reference in the registration statements, as amended, on Form S-3ASR (Registration No. 333-261165) and Form S-8 (Registration Nos. 333-106620, 333-129032, 333-136333, 333-174721, 333-205756, 333-238071, and 333-257917) of our reports dated February 23, 2023, with respect to the consolidated fi

VLO / Valero Energy Corporation / VANGUARD GROUP INC - SCHEDULE 13G/A Passive Investment

SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 Schedule 13G Under the Securities Exchange Act of 1934 (Amendment No.: 9)* Name of issuer: Valero Energy Corp. Title of Class of Securities: Common Stock CUSIP Number: 91913Y100 Date of Event Which Requires Filing of this Statement: December 30, 2022 Check the appropriate box to designate the rule pursuant to which this Schedule is filed: ☒

VLO / Valero Energy Corporation / STATE STREET CORP Passive Investment

UNITED STATES SECURITIES AND EXCHANGE COMMISSION WASHINGTON, D.C. 20549 SCHEDULE 13G UNDER THE SECURITIES EXCHANGE ACT OF 1934 AMENDED FILING VALERO ENERGY CORP (NAME OF ISSUER) COMMON STOCK (TITLE OF CLASS OF SECURITIES) 91913Y100 (CUSIP NUMBER) 12/31/2022 (DATE OF EVENT WHICH REQUIRES FILING OF THIS STATEMENT) CHECK THE APPROPRIATE BOX TO DESIGNATE THE RULE PURSUANT TO WHICH THIS SCHEDULE IS FIL

Financial Statements and Exhibits, Results of Operations and Financial Condition

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): January 26, 2023 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commiss

Valero Energy Reports 2022 Fourth Quarter and Full Year Results

Exhibit 99.01 Valero Energy Reports 2022 Fourth Quarter and Full Year Results •Reported net income attributable to Valero stockholders of $3.1 billion, or $8.15 per share, for the fourth quarter and $11.5 billion, or $29.04 per share, for the year •Reported adjusted net income attributable to Valero stockholders of $3.2 billion, or $8.45 per share, for the fourth quarter and $11.6 billion, or $29.

VLO / Valero Energy Corporation / BlackRock Inc. Passive Investment

SC 13G/A 1 us91913y1001012423.txt us91913y1001012423.txt SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 13G Under the Securities Exchange Act of 1934 (Amendment No: 13) VALERO ENERGY CORP - (Name of Issuer) Common Stock - (Title of Class of Securities) 91913Y100 - (CUSIP Number) December 31, 2022 - (Date of Event Which Requires Filing of this Statement) Check the appropriate bo

$4,000,000,000 5-YEAR FIFTH AMENDED AND RESTATED REVOLVING CREDIT AGREEMENT dated as of November 22, 2022 VALERO ENERGY CORPORATION, The Lenders Party Hereto JPMORGAN CHASE BANK, N.A., as Administrative Agent CITIBANK, N.A. MIZUHO BANK, LTD., as Co-S

EX-99.1 Exhibit 99.1 EXECUTION VERSION $4,000,000,000 5-YEAR FIFTH AMENDED AND RESTATED REVOLVING CREDIT AGREEMENT dated as of November 22, 2022 among VALERO ENERGY CORPORATION, The Lenders Party Hereto and JPMORGAN CHASE BANK, N.A., as Administrative Agent CITIBANK, N.A. and MIZUHO BANK, LTD., as Co-Syndication Agents and BANK OF AMERICA, N.A., THE BANK OF NOVA SCOTIA, MUFG BANK, LTD., SUMITOMO M

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): November 22, 2022 VALERO ENERGY C

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): November 22, 2022 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 1-13175 74-1828067 (State or other jurisdiction of incorporation) (Commissi

Valero Energy Corporation Elects Marie A. Ffolkes to Board of Directors

Exhibit 99.1 Valero Energy Corporation Elects Marie A. Ffolkes to Board of Directors SAN ANTONIO, October 31, 2022 ? Valero Energy Corporation (NYSE: VLO, ?Valero?) announced today that Marie A. Ffolkes has been elected as an independent director to Valero?s board of directors (the ?Board?) and has joined the Board?s Nominating and Corporate Governance Committee, effective immediately. Ms. Ffolkes

Regulation FD Disclosure, Departure of Directors or Certain Officers; Election of Directors; Appointment of Certain Officers; Compensatory Arrangements of Certain Officers, Financial Statements and Exhibits

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): October 28, 2022 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 1-13175 74-1828067 (State or other jurisdiction of incorporation) (Commissio

Section 1350 Certifications (under Section 906 of the Sarbanes-Oxley Act of 2002).

Exhibit 32.01 CERTIFICATION PURSUANT TO 18 U.S.C. SECTION 1350, AS ADOPTED PURSUANT TO SECTION 906 OF THE SARBANES-OXLEY ACT OF 2002 In connection with the Quarterly Report of Valero Energy Corporation (the Company) on Form 10-Q for the quarter ended September 30, 2022, as filed with the Securities and Exchange Commission on the date hereof (the Report), the undersigned hereby certifies, pursuant

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q (Mark One) ☑ QUARTERLY REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the quarterly period ended September 30, 2022 OR ☐ TRANSITION REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to Commission File Number 001-13175 VALERO

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal executive officer.

Exhibit 31.01 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Joseph W. Gorder, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal financial officer.

Exhibit 31.02 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Jason W. Fraser, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances u

Valero Energy Reports Third Quarter 2022 Results

Exhibit 99.01 Valero Energy Reports Third Quarter 2022 Results ?Reported net income attributable to Valero stockholders of $2.8 billion, or $7.19 per share ?Reported adjusted net income attributable to Valero stockholders of $2.8 billion, or $7.14 per share ?Reduced debt by $1.25 billion in September, bringing Valero?s aggregate debt reduction since the second half of 2021 to approximately $3.6 bi

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): October 25, 2022 VALERO ENERGY CO

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): October 25, 2022 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commiss

Regulation FD Disclosure

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): September 26, 2022 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 1-13175 74-1828067 (State or other jurisdiction of incorporation) (Commiss

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal financial officer.

Exhibit 31.02 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Jason W. Fraser, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances u

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q (Mark One) ? QUARTERLY REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the quarterly period ended June 30, 2022 OR ? TRANSITION REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to Commission File Number 001-13175 VALERO ENER

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal executive officer.

Exhibit 31.01 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Joseph W. Gorder, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances

Section 1350 Certifications (under Section 906 of the Sarbanes-Oxley Act of 2002).

Exhibit 32.01 CERTIFICATION PURSUANT TO 18 U.S.C. SECTION 1350, AS ADOPTED PURSUANT TO SECTION 906 OF THE SARBANES-OXLEY ACT OF 2002 In connection with the Quarterly Report of Valero Energy Corporation (the Company) on Form 10-Q for the quarter ended June 30, 2022, as filed with the Securities and Exchange Commission on the date hereof (the Report), the undersigned hereby certifies, pursuant to 18

Financial Statements and Exhibits, Results of Operations and Financial Condition

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): July 28, 2022 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commission

Valero Energy Reports Second Quarter 2022 Results

Exhibit 99.01 Valero Energy Reports Second Quarter 2022 Results ?Reported net income attributable to Valero stockholders of $4.7 billion, or $11.57 per share ?Reported adjusted net income attributable to Valero stockholders of $4.6 billion, or $11.36 per share ?Reduced debt by $300 million through the acquisition of the 4.00 percent Gulf Opportunity Zone Revenue Bonds (GO Zone Bonds), reducing Val

Regulation FD Disclosure

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): July 7, 2022 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 1-13175 74-1828067 (State or other jurisdiction of incorporation) (Commission Fi

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 11-K ANNUAL REPORT PURSUANT TO SECTION 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the fiscal year ended December 31, 2021 Commission File Number 001-13175 PREMCOR RETI

11-K 1 pcoretsavingsplan11-k2021.htm PREMCOR RETIREMENT SAVINGS PLAN 2021 FORM 11-K UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 11-K ANNUAL REPORT PURSUANT TO SECTION 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the fiscal year ended December 31, 2021 Commission File Number 001-13175 PREMCOR RETIREMENT SAVINGS PLAN VALERO ENERGY CORPORATION One Valero Way San A

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 11-K ANNUAL REPORT PURSUANT TO SECTION 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the fiscal year ended December 31, 2021 Commission File Number 001-13175 VALERO ENERG

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 11-K ANNUAL REPORT PURSUANT TO SECTION 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the fiscal year ended December 31, 2021 Commission File Number 001-13175 VALERO ENERGY CORPORATION THRIFT PLAN VALERO ENERGY CORPORATION One Valero Way San Antonio, Texas 78249 VALERO ENERGY CORPORATION THRIFT PLAN Table of Contents Pa

Consent of Independent Registered Public Accounting Firm

Exhibit 23.01 Consent of Independent Registered Public Accounting Firm We consent to the incorporation by reference in the registration statement (No. 333-136333) on Form S-8 of our report dated June 24, 2022, with respect to the financial statements and the supplemental Schedule H, Line 4i–Schedule of Assets (Held at End of Year) as of December 31, 2021 of the Premcor Retirement Savings Plan. /s/

Consent of Independent Registered Public Accounting Firm

Exhibit 23.01 Consent of Independent Registered Public Accounting Firm We consent to the incorporation by reference in the registration statement (No. 333-257917) on Form S-8 of our report dated June 24, 2022, with respect to the financial statements and the supplemental Schedule H, Line 4i–Schedule of Assets (Held at End of Year) as of December 31, 2021 of the Valero Energy Corporation Thrift Pla

Regulation FD Disclosure, Financial Statements and Exhibits

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): June 1, 2022 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 1-13175 74-1828067 (State or other jurisdiction of incorporation) (Commission Fi

Cautionary Statement This presentation contains forward-looking statements made by Valero Energy Corporation (“VLO” or “Valero”) within the meaning of federal securities laws. These statements discuss future expectations, contain projections of resul

Exhibit 99.01 Advancing the Future of Energy Advancing the Future of Energy ? With Capital Discipline, Innovation and Unmatched Execution W I T H C A P I TA L D I S C I P L I N E , I N N O V AT I O N A N D U N M AT C H E D E X E C U T I O N . R E L I A B L E A F F O R D A B L E S U S T A I N A B L E E N E R G Y Reliable, Affordable and Sustainable Energy I N V E S T O R P R E S E N T A T I O N | J

Departure of Directors or Certain Officers; Election of Directors; Appointment of Certain Officers; Compensatory Arrangements of Certain Officers, Financial Statements and Exhibits, Other Events, Submission of Matters to a Vote of Security Holders

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): April 28, 2022 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 1-13175 74-1828067 (State or other jurisdiction of incorporation) (Commission

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-Q (Mark One) ? QUARTERLY REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the quarterly period ended March 31, 2022 OR ? TRANSITION REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to Commission File Number 001-13175 VALERO ENE

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal executive officer.

Exhibit 31.01 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Joseph W. Gorder, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal financial officer.

Exhibit 31.02 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Jason W. Fraser, certify that: 1.I have reviewed this quarterly report on Form 10-Q of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances u

Section 1350 Certifications (under Section 906 of the Sarbanes-Oxley Act of 2002).

Exhibit 32.01 CERTIFICATION PURSUANT TO 18 U.S.C. SECTION 1350, AS ADOPTED PURSUANT TO SECTION 906 OF THE SARBANES-OXLEY ACT OF 2002 In connection with the Quarterly Report of Valero Energy Corporation (the Company) on Form 10-Q for the quarter ended March 31, 2022, as filed with the Securities and Exchange Commission on the date hereof (the Report), the undersigned hereby certifies, pursuant to 1

Valero Energy Reports First Quarter 2022 Results

Exhibit 99.01 Valero Energy Reports First Quarter 2022 Results ?Reported net income attributable to Valero stockholders of $905 million, or $2.21 per share ?Reported adjusted net income attributable to Valero stockholders of $944 million, or $2.31 per share ?Returned $545 million in cash to stockholders, with $401 million paid as dividends and $144 million of stock buybacks ?Reduced Valero?s long-

Financial Statements and Exhibits, Results of Operations and Financial Condition

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): April 26, 2022 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commissio

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 Filed by the Registrant ? Filed by a party other than the Registrant ? Check the appropriate box: ? Preliminary Proxy Statement ? Confidential, for Use of the Commission Only (as permitted by Rule 14a-6(e)(2)) ? Definitive Proxy State

Notice Of Exempt Solicitation: (VOLUNTARY SUBMISSION)

Notice Of Exempt Solicitation: (VOLUNTARY SUBMISSION) NAME OF REGISTRANT: Valero Energy NAME OF PERSON RELYING ON EXEMPTION: Majority Action ADDRESS OF PERSON RELYING ON EXEMPTION: PO Box 4831, Silver Spring, MD 20914 Written materials are submitted pursuant to Rule 14a-6(g)(1) promulgated under the Securities Exchange Act of 1934.

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934

DEFA14A 1 valero2022proxyshproposaln.htm DEFINITIVE ADDITIONAL PROXY SOLICITING MATERIALS UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 Filed by the Registrant ☒ Filed by a party other than the Registrant ☐ Check the appropriate box: ☐ Preliminary Proxy Statement ☐ Confidential,

Marked comparison of Amended and Restated Bylaws of Valero Energy Corporation (indicating the Amendments).

Exhibit 3.02 VALERO ENERGY CORPORATION BYLAWS (Amended and Restated effective as of September 20, 2017 March 15, 2022) ARTICLE I. MEETINGS OF STOCKHOLDERS Section 1. Date, Time and Location of Annual Meeting. The annual meeting of stockholders shall be held at such date and time and at such place as shall be designated from time to time by the Board of Directors and stated in the notice of the mee

Amendments to Articles of Incorporation or Bylaws; Change in Fiscal Year, Financial Statements and Exhibits

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): March 15, 2022 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commissio

Amended and Restated Bylaws of Valero Energy Corporation–incorporated by reference to Exhibit 3.01 to Valero’s current report on Form 8-K dated March 15, 2022 and filed March 18, 2022 (SEC File No. 001-13175)

Exhibit 3.01 VALERO ENERGY CORPORATION BYLAWS (Amended and Restated effective as of March 15, 2022) ARTICLE I. MEETINGS OF STOCKHOLDERS Section 1. Date, Time and Location of Annual Meeting. The annual meeting of stockholders shall be held at such date and time and at such place as shall be designated from time to time by the Board of Directors and stated in the notice of the meeting for the purpos

Valero Energy Corporation Vote Yes: Proposal #4 “Report On Near- And Long-Term Greenhouse Gas Emissions Targets” Annual Meeting: April 28, 2022

Valero Energy Corporation Vote Yes: Proposal #4 ?Report On Near- And Long-Term Greenhouse Gas Emissions Targets? Annual Meeting: April 28, 2022 CONTACT: Mary Minette, Mercy Investment Services | mminette@mercyinvestments.

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 Filed by the Registrant ? Filed by a party other than the Registrant ? Check the appropriate box: ? Preliminary Proxy Statement ? Confidential, for Use of the Commission Only (as permitted by Rule 14a-6(e)(2)) ? Definitive Proxy State

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934

Table of Contents UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 14A Proxy Statement Pursuant to Section 14(a) of the Securities Exchange Act of 1934 Filed by the Registrant ☒ Filed by a party other than the Registrant ☐ Check the appropriate box: ☐ Preliminary Proxy Statement ☐ Confidential, for Use of the Commission Only (as permitted by Rule 14a-6(e)(2)) ☒ Defi

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-K

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 10-K (Mark One) ? ANNUAL REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the fiscal year ended December 31, 2021 OR ? TRANSITION REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to Commission file number 001-13175 VALERO ENERGY C

Valero Energy Corporation subsidiaries.

Exhibit 21.01 Subsidiaries of Valero Energy Corporation as of February 18, 2022 Name of Entity State of Incorporation/ Organization AIR BP-PBF DEL PERU SAC Peru BELFAST STORAGE LTD Northern Ireland CANADIAN ULTRAMAR COMPANY Nova Scotia COLONNADE INSURANCE COMPANY Texas DIAMOND ALTERNATIVE ENERGY, LLC Delaware DIAMOND ALTERNATIVE ENERGY OF CANADA INC. Canada DIAMOND GREEN DIESEL HOLDINGS LLC Delawa

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal executive officer.

Exhibit 31.01 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Joseph W. Gorder, certify that: 1.I have reviewed this annual report on Form 10-K of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances und

Form of Restricted Stock Agreement (current)–incorporated by reference to Exhibit 10.26 to Valero’s annual report on Form 10-K for the year ended December 31, 2021 (SEC File No. 001-13175).

Exhibit 10.26 RESTRICTED STOCK AGREEMENT Valero Energy Corporation 2020 Omnibus Stock Incentive Plan This Restricted Stock Agreement (this ?Agreement?) is between Valero Energy Corporation, a Delaware corporation (?Valero?), and [], an employee of Valero or one of its Affiliates (?Employee?), who agree as follows: 1.Introduction. Pursuant to the Valero Energy Corporation 2020 Omnibus Stock Incenti

Consent of KPMG LLP dated February 22, 2022.

Exhibit 23.01 Consent of Independent Registered Public Accounting Firm We consent to the incorporation by reference in the registration statements, as amended, on Form S-3ASR (Registration No. 333-261165) and Form S-8 (Registration Nos. 333-106620, 333-129032, 333-136333, 333-174721, 333-205756, 333-238071, and 333-257917) of our reports dated February 22, 2022, with respect to the consolidated fi

Section 1350 Certifications (under Section 906 of the Sarbanes-Oxley Act of 2002).

Exhibit 32.01 CERTIFICATION PURSUANT TO 18 U.S.C. SECTION 1350, AS ADOPTED PURSUANT TO SECTION 906 OF THE SARBANES-OXLEY ACT OF 2002 In connection with the Annual Report of Valero Energy Corporation (the Company) on Form 10-K for the year ended December 31, 2021, as filed with the Securities and Exchange Commission on the date hereof (the Report), the undersigned hereby certifies, pursuant to 18 U

Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal financial officer.

Exhibit 31.02 CERTIFICATION PURSUANT TO SECTION 302 OF THE SARBANES-OXLEY ACT OF 2002 I, Jason W. Fraser, certify that: 1.I have reviewed this annual report on Form 10-K of Valero Energy Corporation; 2.Based on my knowledge, this report does not contain any untrue statement of a material fact or omit to state a material fact necessary to make the statements made, in light of the circumstances unde

Amendment No. 1 to the Valero Energy Corporation 2020 Omnibus Stock Incentive Plan effective October 1, 2021–incorporated by reference to Exhibit 10.04 to Valero’s annual report on Form 10-K for the year ended December 31, 2021 (SEC File No. 001-13175).

Exhibit 10.04 AMENDMENT NO. 1 TO THE VALERO ENERGY CORPORATION 2020 OMNIBUS STOCK INCENTIVE PLAN WHEREAS, Valero Energy Corporation (?Valero?) has adopted and maintains the Valero Energy Corporation 2020 Omnibus Stock Incentive Plan (the ?2020 OSIP?) which provides eligible employees and members of the board of directors (the ?Board?) of Valero with additional incentives through the grant of award

VLO / Valero Energy Corporation / VANGUARD GROUP INC - SCHEDULE 13G/A Passive Investment

SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 Schedule 13G Under the Securities Exchange Act of 1934 (Amendment No.: 8)* Name of issuer: Valero Energy Corp. Title of Class of Securities: Common Stock CUSIP Number: 91913Y100 Date of Event Which Requires Filing of this Statement: December 31, 2021 Check the appropriate box to designate the rule pursuant to which this Schedule is filed: ?

Form of the Senior Notes due 2052 (included in Exhibit 4.2 above).

Exhibit 4.2 VALERO ENERGY CORPORATION 4.000% Senior Notes due 2052 A single series of Securities is hereby established pursuant to Section 301 of the Indenture dated as of March 10, 2015 (the ?Indenture?), between Valero Energy Corporation, a Delaware corporation (the ?Company?), and U.S. Bank Trust Company, National Association, as successor in interest to U.S. Bank National Association, as Trust

Underwriting Agreement dated February 2, 2022 among the Company, J.P. Morgan Securities LLC, BofA Securities, Inc., Scotia Capital (USA) Inc. and Wells Fargo Securities, LLC, as representatives of the several underwriters named therein.

Exhibit 1.1 VALERO ENERGY CORPORATION DEBT SECURITIES Underwriting Agreement February 2, 2022 To the Representatives named in Schedule I hereto of the Underwriters named in Schedule II hereto Ladies and Gentlemen: Valero Energy Corporation, a Delaware corporation (the ?Company?), proposes to issue and sell to the underwriters named in Schedule II hereto (the ?Underwriters?), for whom you are actin

Entry into a Material Definitive Agreement, Financial Statements and Exhibits, Creation of a Direct Financial Obligation or an Obligation under an Off-Balance Sheet Arrangement of a Registrant

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): February 2, 2022 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commiss

Calculation of Filing Fee Table (Form Type) Valero Energy Corporation (Exact Name of Registrant as Specified in its Charter) Table 1: Newly Registered and Carry Forward Securities Security Type Security Class Title Fee Calculation or Carry Forward Ru

Exhibit 107 Calculation of Filing Fee Table 424(b)(5) (Form Type) Valero Energy Corporation (Exact Name of Registrant as Specified in its Charter) Table 1: Newly Registered and Carry Forward Securities Security Type Security Class Title Fee Calculation or Carry Forward Rule Amount Registered Proposed Maximum Offering Price Per Unit Maximum Aggregate Offering Price Fee Rate Amount of Registration Fee(1) Carry Forward Form Type Carry Forward File Number Carry Forward Initial Effective Date Filing Fee Previously Paid In Connection with Unsold Securities to be Carried Forward Newly Registered Securities Fees to Be Paid Debt 4.

Valero Energy Corporation $650,000,000 4.000% Senior Notes due 2052

Table of Contents Filed Pursuant to Rule 424(b)(5) Registration No. 333-261165 PROSPECTUS SUPPLEMENT (To Prospectus dated November 18, 2021) Valero Energy Corporation $650,000,000 4.000% Senior Notes due 2052 This is an offering of $650,000,000 aggregate principal amount of our 4.000% Senior Notes due 2052 (the ?notes?). The notes will mature on June 1, 2052. Interest on the notes will be payable

SUBJECT TO COMPLETION, DATED FEBRUARY 2, 2022

Table of Contents The information in this preliminary prospectus supplement is not complete and may be changed.

Valero Energy Corporation Pricing Term Sheet $650,000,000 4.000% Senior Notes due 2052 Issuer: Valero Energy Corporation (the “Company”) Ratings*: Baa2 (negative) (Moody’s) / BBB (stable) (S&P) / BBB (stable) (Fitch) Pricing Date: February 2, 2022 Se

Free Writing Prospectus Filed Pursuant to Rule 433 Registration Statement No. 333-261165 February 2, 2022 Valero Energy Corporation Pricing Term Sheet $650,000,000 4.000% Senior Notes due 2052 Issuer: Valero Energy Corporation (the ?Company?) Ratings*: Baa2 (negative) (Moody?s) / BBB (stable) (S&P) / BBB (stable) (Fitch) Pricing Date: February 2, 2022 Settlement Date: February 7, 2022 (T+3) Denomi

VLO / Valero Energy Corporation / BlackRock Inc. Passive Investment

us91913y1001020122.txt SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 SCHEDULE 13G Under the Securities Exchange Act of 1934 (Amendment No: 12) VALERO ENERGY CORP - (Name of Issuer) Common Stock - (Title of Class of Securities) 91913Y100 - (CUSIP Number) December 31, 2021 - (Date of Event Which Requires Filing of this Statement) Check the appropriate box to designate the rule pursuant t

Financial Statements and Exhibits, Results of Operations and Financial Condition

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of The Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): January 27, 2022 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commiss

Valero Energy Reports 2021 Fourth Quarter and Full Year Results

Exhibit 99.01 Valero Energy Reports 2021 Fourth Quarter and Full Year Results ?Reported net income attributable to Valero stockholders of $1,009 million, or $2.46 per share, for the fourth quarter and $930 million, or $2.27 per share, for the year. ?Reported adjusted net income attributable to Valero stockholders of $1,012 million, or $2.47 per share, for the fourth quarter and $1,152 million, or

Form of the 2051 notes (included in Exhibit 4.4 above).

Exhibit 4.4 VALERO ENERGY CORPORATION 3.650% Senior Notes due 2051 A single series of Securities is hereby established pursuant to Section 301 of the Indenture dated as of March 10, 2015 (the ?Indenture?), between Valero Energy Corporation, a Delaware corporation (the ?Company?), and U.S. Bank National Association, as Trustee (in such capacity, the ?Trustee?), as follows (capitalized terms used an

Form of the 2031 notes (included in Exhibit 4.2 above).

Exhibit 4.2 VALERO ENERGY CORPORATION 2.800% Senior Notes due 2031 A single series of Securities is hereby established pursuant to Section 301 of the Indenture dated as of March 10, 2015 (the ?Indenture?), between Valero Energy Corporation, a Delaware corporation (the ?Company?), and U.S. Bank National Association, as Trustee (in such capacity, the ?Trustee?), as follows (capitalized terms used an

Entry into a Material Definitive Agreement, Financial Statements and Exhibits, Creation of a Direct Financial Obligation or an Obligation under an Off-Balance Sheet Arrangement of a Registrant

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): November 29, 2021 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commis

Financial Statements and Exhibits, Other Events

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): November 18, 2021 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commis

Underwriting Agreement dated November 18, 2021 among the Company, Citigroup Global Markets Inc., J.P. Morgan Securities LLC, Mizuho Securities USA LLC and SMBC Nikko Securities America, Inc., as representatives of the several underwriters named therein.

Exhibit 1.1 VALERO ENERGY CORPORATION DEBT SECURITIES Underwriting Agreement November 18, 2021 To the Representatives named in Schedule I hereto of the Underwriters named in Schedule II hereto Ladies and Gentlemen: Valero Energy Corporation, a Delaware corporation (the ?Company?), proposes to issue and sell to the underwriters named in Schedule II hereto (the ?Underwriters?), for whom you are acti

Valero Energy Corporation Pricing Term Sheet $500,000,000 2.800% Senior Notes due 2031 $950,000,000 3.650% Senior Notes due 2051 Issuer: Valero Energy Corporation (the “Company”) Ratings*: Baa2 (negative) (Moody’s) / BBB (stable) (S&P) / BBB (stable)

FWP Free Writing Prospectus Filed Pursuant to Rule 433 Registration Statement No. 333-261165 November 18, 2021 Valero Energy Corporation Pricing Term Sheet $500,000,000 2.800% Senior Notes due 2031 $950,000,000 3.650% Senior Notes due 2051 Issuer: Valero Energy Corporation (the “Company”) Ratings*: Baa2 (negative) (Moody’s) / BBB (stable) (S&P) / BBB (stable) (Fitch) Pricing Date: November 18, 202

CALCULATION OF REGISTRATION FEE Title of Securities to be Registered Amount to be Registered Proposed Maximum Offering per Unit Maximum Aggregate Offering Price Amount of Registration Fee(1)(2) 2.800% Senior Notes due 2031 $500,000,000 99.749% $498,7

Table of Contents Filed Pursuant to Rule 424(b)(5) Registration Statement No. 333-261165 CALCULATION OF REGISTRATION FEE Title of Securities to be Registered Amount to be Registered Proposed Maximum Offering per Unit Maximum Aggregate Offering Price Amount of Registration Fee(1)(2) 2.800% Senior Notes due 2031 $500,000,000 99.749% $498,745,000 $46,233.66 3.650% Senior Notes due 2051 $950,000,000 9

Regulation FD Disclosure, Financial Statements and Exhibits

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM 8-K CURRENT REPORT Pursuant to Section 13 or 15(d) of the Securities Exchange Act of 1934 Date of Report (Date of earliest event reported): November 18, 2021 VALERO ENERGY CORPORATION (Exact name of registrant as specified in its charter) Delaware 001-13175 74-1828067 (State or other jurisdiction of incorporation) (Commis

Valero Energy Corporation Announces Cash Tender Offers for Certain Outstanding Notes

Exhibit 99.1 Valero Energy Corporation Announces Cash Tender Offers for Certain Outstanding Notes November 18, 2021 ? Valero Energy Corporation (NYSE: VLO, ?Valero?) announced today that it has commenced tender offers (each individually, with respect to a series of notes, a ?Tender Offer,? and collectively, the ?Tender Offers?) to purchase for cash (1) any and all of its outstanding 2.700% Senior